KOPRI Repository

Nitrite-Induced Activation of Iodate into Molecular Iodine in Frozen Solution

Cited 1 time in wos
Cited 1 time in scopus
Metadata Downloads
Title
Nitrite-Induced Activation of Iodate into Molecular Iodine in Frozen Solution
Other Titles
얼음상 아질산염과 요오도산염의 화학반응연구
Authors
Kim, Kitae
Ju, Jinjung
Kim, Bomi
Chung, Hyun Young
Vetrakova, L'ubica
Heger, Dominik
Saiz-Lopez, Alfonso
Choi, Wonyong
Kim, Jungwon
Subject
Engineering; Environmental Sciences & Ecology
Keywords
iodate reduction; nitrite oxidation; redox chemistry in ice
Issue Date
2019-05
Citation
Kim, Kitae, et al. 2019. "Nitrite-Induced Activation of Iodate into Molecular Iodine in Frozen Solution". ENVIRONMENTAL SCIENCE & TECHNOLOGY, 53(1): 4892-4900.
Abstract
A new mechanism for the abiotic production of molecular iodine (I2) from iodate (IO3?), which is the most abundant iodine species, in dark conditions was identified and investigated. The production of I2 in aqueous solution containing IO3? and nitrite (NO2?) at 25 °C was negligible. However, the redox chemical reaction between IO3? and NO2? rapidly proceeded in frozen solution at ?20 °C, which resulted in the production of I2, I?, and NO3?. The rapid redox chemical reaction between IO3? and NO2? in frozen solution is ascribed to the accumulation of IO3?, NO2?, and protons in the liquid regions between ice crystals during freezing (freeze concentration effect). This freeze concentration effect was verified by confocal Raman microscopy for the solute concentration and UV?visible absorption spectroscopy with cresol red (acid-base indicator) for the proton concentration. The freezing-induced production of I2 in the presence of IO3? and NO2? was observed under various conditions, which suggests this abiotic process for I2 production is not restricted to a specific region and occurs in many cold regions. NO2?-induced activation of IO3? to I2 in frozen solution may help explain why the measured values of iodine are larger than the modeled values in some polar areas.
URI
http://repository.kopri.re.kr/handle/201206/9641
DOI
http://dx.doi.org/10.1021/acs.est.8b06638
ISSN
0013-936X
Files in This Item
General Conditions
      ROMEO Green
    Can archive pre-print and post-print or publisher's version/PDF
      ROMEO Blue
    Can archive post-print (ie final draft post-refereeing) or publisher's version/PDF
      ROMEO Yellow
    Can archive pre-print (ie pre-refereeing)
      ROMEO White
    Archiving not formally supported

    Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

    Browse