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Application of laser-induced breakdown spectroscopy to Arctic sediments in the Chukchi Sea

Cited 5 time in wos
Cited 4 time in scopus
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Title
Application of laser-induced breakdown spectroscopy to Arctic sediments in the Chukchi Sea
Other Titles
척치해 북극 퇴적물에 레이저 유도 방전 현상 분광법 적용연구
Authors
Han, Dukki
Joe, Young Jin
Ryu, Jong-Sik
Uno, Tatsuya
Kim, Gibaek
Yamamoto, Masanobu
Park, Kihong
Hur, Hor-Gil
Lee, Ji-Hoon
Nam, Seung-il
Subject
Spectroscopy
Keywords
Chukchi Sea; LIBS; Sediment composition; Western Arctic sediment; XRF-core scanning
Issue Date
2018-08
Citation
Han, Dukki, et al. 2018. "Application of laser-induced breakdown spectroscopy to Arctic sediments in the Chukchi Sea". SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 146(1): 84-92.
Abstract
Physical and geochemical investigations coupled with laser-induced breakdown spectroscopy (LIBS) were performed on three surface sediment cores (ARA02B/01A, ARA02B/02, and ARA02B/03A) recovered from the western Arctic Ocean (Chukchi Sea) during the IBRV ARAON 2011 expedition. The LIBS technique was applied to conduct elemental analysis of the Arctic sediments and compare the results to those obtained using an X-ray fluorescence (XRF) core scanner and inductively coupled plasma (ICP) system. The LIBS technique showed an elemental composition similar to that using XRF and ICP in each sediment core. Qualitative and semi-quantitative LIBS analyses provide distinguishable patterns between sediment cores, similar to those observed in the ICP analysis. In particular, the elemental pattern of LIBS responded to the color change of the sediment cores. Dark brown layers in the upper parts of the cores were indicated by the color indices and showed elevated Mn/Al ratios, suggesting the influence of regional variation in terrestrial input since the deglacial period. In this study, grain size distribution and contents of detrital dolomite and organic carbon as well as elemental composition (LIBS) were considered to determine sediment provenance and sedimentation environments during the Holocene. Furthermore, the present study showed that the LIBS technique may be used as an applicable method to unravel regional variations in sedimentary composition in the Arctic Ocean.
URI
https://repository.kopri.re.kr/handle/201206/10514
DOI
http://dx.doi.org/10.1016/j.sab.2018.05.002
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